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Sviluppo di nuovi sistemi catalitici dei metalli del gruppo 4 per la polimerizzazione di monomeri olefinici e polari
(Universita degli studi di Salerno, 2016-03-18)
In this PhD work, a series of eight new group 4 metal complexes 1−8 (1 = (t- BuOS)2TiCl2; 2 = (CumOS)2TiCl2; 3 = (t-BuOS)2Zr(CH2Ph)2; 4 = (CumOS)2Zr(CH2Ph)2); 5 = (t-BuOS)2Ti(OiPr)2; 6 = (t-BuOS)2Zr(OtBu)2; 7 = (t- ...
Fluorescence-based sensors for the detection of biologically and environmentally relevant molecules
(Universita degli studi di Salerno, 2016-03-15)
Hydrogen sulfide (H2S) has been known for long time as a toxic molecule in biological systems. More recent studies have shown that mammals can produce H2S in a controlled fashion, suggesting that it’s important in maintaining ...
Biodegradable and functional aliphatic co-polyesters
(Universita degli studi di Salerno, 2016-03-15)
Over the past decades, aliphatic polyesters have found rapidly increasing interest. Linear aliphatic polyesters, such as poly(glycolide) (PGA), poly(lactide) (PLA), poly(ε−caprolactone) (PCL) and their copolymers have found ...
Sustainable catalysis by polymer supported gold nanoparticles
(Universita degli studi di Salerno, 2016-03-16)
Gold Nanoparticles are nanomaterials whose properties are completely different from the ones of the bulk material. Nowadays many chemists have been using them as catalysts which work under mild conditions and respect the ...