Sfoglia Chimica per Titolo
Items 17-36 di 81
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Design e sintesi di analoghi delle azumammidi, potenti inibitori degli enzimi HDACs
(Universita degli studi di Salerno, 2011-03-07)Le azumammidi sono cinque ciclopeptidi di origine marina, isolate nel 2003 da Fusetani et al dalla spugna Mycale izuensis e brevettate dalla Yamanouchi Pharmaceutical. L'interesse destato da questi metaboliti secondari ... -
Development and optimization of analytical methods for the analysis of drugs in wastewater samples and chronic aquatic toxicity assessment of the Crustacea Copepoda Tigriopus fulvus
(Universita degli studi di Salerno, 2020-02-13)Pharmaceutical compounds constitute one of the most important emerging classes of environmental pollutants. Recent studies have discovered their occurrence in environmental samples investigated worldwide, including ... -
Development of eco-sustainable methodologies for innovative materials inspired by cellulose fibers
(Universita degli studi di Salerno, 2021-04-28)This PhD is an “Industrial-PhD”, carried out in collaboration between University of Basilicata and LUCART S.p.A (Porcari, Lucca, Italy), in that case with the plant located at Avigliano (Potenza, Italy). The scholarship ... -
Development of iron-based catalysts for the coupling of carbon dioxide with epoxides
(Universita degli studi di Salerno, 2018-03-07)Beside the environmental and energetic issues, carbon dioxide can be considered as a resource. Many chemical transformations based on CO2 as C-1 building block have been developed. The coupling reaction of epoxides with ... -
Development of molecular models of interfaces using a multi-scale hybrid particle-field approach: application to composite materials and biomembranes
(Universita degli studi di Salerno, 2014-03-07)The rule of the interface in systems including polymer composites and block-‐ copolymer interacting with biomembrane has been investigated by computational approach. In particular, for the poly ... -
Development of new in vitro models based on the use of electrospun scaffolds and their imaging by multiphoton microscopy coupled with fluorescence lifetime imaging microscopy
(Universita degli studi di Salerno, 2018-02-22)In this thesis, new possible applications of electrospun scaffolds are presented. Besides, the interaction of human dermal fibroblasts (HDFs) with the materials has been investigated using multiphoton microscopy (MPM) ... -
Dynamical control of engineered stimuli-responsive materials: synthesis and optimization of active micro-vesicles
(Universita degli studi di Salerno, 2020-02-14)The aim of this PhD project is the combination of a pH clock reaction (the enzymatic urea-urease reaction) with pH-responsive materials to generate a chemo-mechanical coupling. A clock reaction is characterized by a ... -
Effect of thermo wood modification and polyoxometalates catalysts on yield and extractives composition
(Universita degli studi di Salerno, 2019-02-06)The aims of this work were to investigate the impact of the heat treatment on the chemical composition (holocellulose, lignin and extractives) of different wood species, to characterise and quantify wood extractives and ... -
Enantioselective construction of new heterocyclic scaffolds via organocatalyzed cascade reactions
(Universita degli studi di Salerno, 2019-02-04)Chirality plays a vital role in human daily life. After the famous but tragic case regarding the Thalidomide, Food and Drug Administration (FDA) gave a guide in relation to the submission of new drug applications... [edited ... -
Environmental and catalytic applications of alkaline oxides
(Universita degli studi di Salerno, 2015-04-20)Alkaline oxides are widely used in industrial processes involving removal of gaseous compounds as unwanted by-products such as CO2, hydrogen sulphide and nitric oxides. Traditional processes generally involve Ca-based ... -
Enzymatic synthesis of macrolactones
(Universita degli studi di Salerno, 2011-02-24)Macrolactones are a large and structurally diverse class of compounds. Natural products having a macrolactone structure have been isolated from many natural sources such as plants, insects, marine organism and bacteria. ... -
Fluorescence-based sensors for the detection of biologically and environmentally relevant molecules
(Universita degli studi di Salerno, 2016-03-15)Hydrogen sulfide (H2S) has been known for long time as a toxic molecule in biological systems. More recent studies have shown that mammals can produce H2S in a controlled fashion, suggesting that it’s important in maintaining ... -
Functionalized Syndiotactic Polystyrene
(Universita degli studi di Salerno, 2012-02-14)La sintesi di materiali polimerici da metodo di modificazione, per ottenere le proprietà desiderate in polimeri, è un argomento importante in chimica dei polimeri e tecnologia. Molto spesso, proprietà desiderate non sono ... -
Heterocyclic architecture for the synthesis of anti-HIV protease and anti-cancer compounds
(Universita degli studi di Salerno, 2020-02-14)Introduction of heterocycle moieties in a bioactive molecule can have important effects on physicochemical and pharmacological properties, because of their chemical stability, their structural rigidity and due to the ... -
Innovative applications of stable carbon isotope ratio in environmental and food chemistry
(Universita degli studi di Salerno, 2018-03-08)In the last year, the stable isotope ratio analysis has become a useful tool with many applications in different scientific area. In particular the characteristic isotope signature of materials has permitted to identify ... -
Integrated techniques for remediation of dense chlorinated solvents polluted sites
(Universita degli studi di Salerno, 2018-03-08)Trichloroethylene (TCE) is a halogenated aliphatic organic compound frequently detected as pollutant in soils and ground water. A multidisciplinary approach is often required to remediate TCE polluted sites and this PhD ... -
Isolation and characterization of lignins from Wheat straw and cardoon biomasses
(Universita degli studi di Salerno, 2023-03-13)The progressive reduction in the availability of oil resources, the unstoppable increase in their costs and the growing need for efficient environmental protection, imply an urgent development of new technologies for the ... -
Materiali ibridi e nanostrutturati derivati da copolimeri multiblocco polistirene-polibutadiene: sintesi e applicazioni
(Universita degli studi di Salerno, 2012-02-16)Scopo della presente tesi di Dottorato di Ricerca in Chimica, avente ampio carattere di esplorazione e innovazione, è stato quello di sviluppare materiali ibridi di natura organica ed inorganica con controllo della morfologia ... -
Mesoscale Modeling of Carbon Black/Polymer Interfaces: Linking Atomistic and Coarse-Grained Particle-Field Representations
(Universita degli studi di Salerno, 2020-02-11)The research activity, described in this Ph. D. thesis, was dedicated to the development of a novel carbon black (CB) primary particle model, with accurate morphology, to be used in coarse-grained (CG) molecular dynamics ... -
Metathesis reactions catalyzed by ruthenium complexes for the self-healing of aeronautical materials
(Universita degli studi di Salerno, 2018-03-05)In this PhD thesis work, Ruthenium catalysts were covalently and non-covalently linked to carbon-based nanomaterials, in order to give self-repairing ability to the aeronautical materials. These supported catalysts have ...