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Development and optimization of analytical methods for the analysis of drugs in wastewater samples and chronic aquatic toxicity assessment of the Crustacea Copepoda Tigriopus fulvus
(Universita degli studi di Salerno, 2020-02-13)
Pharmaceutical compounds constitute one of the most important
emerging classes of environmental pollutants. Recent studies have
discovered their occurrence in environmental samples investigated
worldwide, including ...
New perspectives in phase transfer catalysis
(Universita degli studi di Salerno, 2020-02-11)
The increasing demand for the stereoselective synthesis of bioactive compounds in both industrial and academic research has led to the rapid development of a variety of diastereo- and enantio-selective processes using phase ...
Dynamical control of engineered stimuli-responsive materials: synthesis and optimization of active micro-vesicles
(Universita degli studi di Salerno, 2020-02-14)
The aim of this PhD project is the combination of a pH clock reaction (the enzymatic
urea-urease reaction) with pH-responsive materials to generate a chemo-mechanical coupling.
A clock reaction is characterized by a ...
Heterocyclic architecture for the synthesis of anti-HIV protease and anti-cancer compounds
(Universita degli studi di Salerno, 2020-02-14)
Introduction of heterocycle moieties in a bioactive molecule can have important effects on physicochemical and pharmacological properties, because of their chemical stability, their structural rigidity and due to the ...
Solid state dynamic behaviour of organic molecules
(Universita degli studi di Salerno, 2020-02-13)
The main interactions characterizing the crystals of organic molecules are weak interactions such
as hydrogen bonds, van der Waals forces, hydrophobic interactions, etc.1
Considering the weak nature of the forces involved, ...
Chiral Bioactive Cyclopeptoids: Concepts and Purposes
(Universita degli studi di Salerno, 2020-02-09)
Peptides are an endless source of inspiration for medicinal chemistry, as these biomacromolecules regulate a number of biological activities, acting as hormones, neurotransmitters, signalling molecules and so on. They show ...
Mesoscale Modeling of Carbon Black/Polymer Interfaces: Linking Atomistic and Coarse-Grained Particle-Field Representations
(Universita degli studi di Salerno, 2020-02-11)
The research activity, described in this Ph. D. thesis, was dedicated to the development of a novel carbon black (CB) primary particle model, with accurate morphology, to be used in coarse-grained (CG) molecular dynamics ...
Stereoselectivity in asymmetric processes and molecular assemblies
(Universita degli studi di Salerno, 2020-02-19)
The aim of this thesis was to explore different areas of organic chemistry in which the
stereocontrol in the design of chemical processes and/or molecular assemblies is necessary.
Therefore, the stereoselectivity in ...