Utilizza questo identificativo per citare o creare un link a questo documento: http://elea.unisa.it/xmlui/handle/10556/6467
Titolo: Stereoselectivity in asymmetric processes and molecular assemblies
Autore: Marsico, Giulia
Zanasi, Riccardo
Superchi, Stefano
Scafato, Patrizia
Parole chiave: Stereoselectivity;Carbolithiation;Cyclochirality
Data: 19-feb-2020
Editore: Universita degli studi di Salerno
Abstract: The aim of this thesis was to explore different areas of organic chemistry in which the stereocontrol in the design of chemical processes and/or molecular assemblies is necessary. Therefore, the stereoselectivity in asymmetric organometallic syntheses, in total synthesis of bioactive natural products and in the formation of chiral arrangements due to intramolecular hydrogen bonding networks have been investigated. In particular, three different projects were faced in this thesis. The methodological study of carbolithiation reaction of 1-aryl-1-alkenyl N,N’-diethylcarbamates, also in enantioselective manner, the asymmetric synthesis of natural products with phytotoxic activity and, finally, the synthesis and the NMR analysis of cyclic triureas showing cyclochirality by virtue of cyclic hydrogen-bonding array only. .. [edited by the Author]
Descrizione: 2018 - 2019
URI: http://elea.unisa.it:8080/xmlui/handle/10556/6467
http://dx.doi.org/10.14273/unisa-4539
È visualizzato nelle collezioni:Chimica

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