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Metathesis reactions catalyzed by ruthenium complexes for the self-healing of aeronautical materials
(Universita degli studi di Salerno, 2018-03-05)
In this PhD thesis work, Ruthenium catalysts were covalently and non-covalently linked to carbon-based nanomaterials, in order to give self-repairing ability to the aeronautical materials. These supported catalysts have ...
New metal catalysts for the synthesis of polyolefins and bioderived polymers
(Universita degli studi di Salerno, 2018-02-28)
The aim of PhD project is the synthesis of new metal catalysts active in the polymerization of polar
monomer and α-olefins. In the last decade, transition metal complexes bearing tetradentate bis(phenolato)
ligands are ...
Carbon-based nanomaterials
(Universita degli studi di Salerno, 2017-02-27)
New layered carbon-based materials were prepared and exhaustively characterized exploiting different characterization techniques, such as thermogravimetry (TGA), differential thermal calorimetry (DSC), Fourier transform ...
Biodegradable and functional aliphatic co-polyesters
(Universita degli studi di Salerno, 2016-03-15)
Over the past decades, aliphatic polyesters have found rapidly increasing interest. Linear aliphatic polyesters, such as poly(glycolide) (PGA), poly(lactide) (PLA), poly(ε−caprolactone) (PCL) and their copolymers have found ...
Ruthenium metathesis precatalysts with unsymmetrical Nheterocyclic carbene (NHC) ligands
(Universita degli studi di Salerno, 2018-03-07)
Olefin metathesis is one of the most important chemical transformations for the formation
of carbon-carbon double bonds. The possibility to build up highly funtionalised alkenes
starting from simple olefins makes this ...
Computational design of new antimicrobial peptides
(Universita degli studi di Salerno, 2018-04-13)
Antimicrobial peptides (AMP) are evolutionarily conserved components of the
innate immune system. They have a broad spectrum of action against bacteria,
fungi and viruses. Therefore, AMP are studied as probable substitutes ...
Redox proteins for the development of biosensors
(Universita degli studi di Salerno, 2011-02-21)
In recent years the field of chemical sensors and optical biosensors has been developed considereably. A biosensor is a device composed of a biological component (Borisov and Wolfbeis 2008) that interacts with a target ...
New catalysts for ring-opening polymerization of cyclic esters
(Universita degli studi di Salerno, 2012-02-16)
The Ring-Opening Polymerization of cyclic esters by metal complexes via coordination-insertion mechanism represents the most effective and versatile method for preparing aliphatic polyesters with a good control in terms ...
Synthesis,characterization and catalytic activity of organometallic complexes of group 3 and 4 with N-heterocyclic carbene ligands
(Universita degli studi di Salerno, 2011-02-21)
The synthesis and characterization of a zirconium complex, having two alkoxide funtionalized N-heterocyclic carbene ligands, and its behaviour as catalyst in the polymerization of ethylene and propylene, have been ...
Materiali ibridi e nanostrutturati derivati da copolimeri multiblocco polistirene-polibutadiene: sintesi e applicazioni
(Universita degli studi di Salerno, 2012-02-16)
Scopo della presente tesi di Dottorato di Ricerca in Chimica, avente ampio carattere di esplorazione e innovazione, è stato quello di sviluppare materiali ibridi di natura organica ed inorganica con controllo della morfologia ...