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Development of dosimeters with selective materials to high frequency radiation
(Universita degli studi di Salerno, 2013-01-23)
The clinical use of ionizing radiation to obtain a necrosing or cytotoxic radiobiological effect on tumoral lesions requires wide and complex physical and dosimetrical procedures. In particular, it is necessary to calculate ...
Design and development of new polymeric materials with potential antimicrobial and/or antifungal activity
(Universita degli studi di Salerno, 2014-12-15)
This PhD project is focused on the development of new polymeric materials with antibacterial and antifungal activity.
The first part of the work was dedicated to the synthesis and the insertion of a modified amino acid ...
Molecular dynamics investigations of drug-cell membrane interactions
(Universita degli studi di Salerno, 2013-04-22)
The cell membrane functions as a platform for the assembly of many signal transduction pathways and provides an additional level of regulation in cell signaling networks.
The complex dynamic structure of the plasma membrane ...
Olefin Metathesis Reactions Promoted by Ru-Catalysts with a Syn Substituted N-heterocyclic Carbene Backbone
(Universita degli studi di Salerno, 2014-03-06)
The development of efficient catalytic systems dedicated to the formation of C−C double bonds from simple to highly functionalized alkenes represents a great challenge in modern organic synthesis. In addressing this ...
Sustainable catalysis by polymer supported gold nanoparticles
(Universita degli studi di Salerno, 2016-03-16)
Gold Nanoparticles are nanomaterials whose properties are completely different from the ones of the bulk material. Nowadays many chemists have been using them as catalysts which work under mild conditions and respect the ...
Fluorescence-based sensors for the detection of biologically and environmentally relevant molecules
(Universita degli studi di Salerno, 2016-03-15)
Hydrogen sulfide (H2S) has been known for long time as a toxic molecule in biological systems. More recent studies have shown that mammals can produce H2S in a controlled fashion, suggesting that it’s important in maintaining ...
Development of iron-based catalysts for the coupling of carbon dioxide with epoxides
(Universita degli studi di Salerno, 2018-03-07)
Beside the environmental and energetic issues, carbon dioxide can
be considered as a resource. Many chemical transformations based
on CO2 as C-1 building block have been developed. The coupling
reaction of epoxides with ...
Sviluppo di nuovi sistemi catalitici dei metalli del gruppo 4 per la polimerizzazione di monomeri olefinici e polari
(Universita degli studi di Salerno, 2016-03-18)
In this PhD work, a series of eight new group 4 metal complexes 1−8 (1 = (t- BuOS)2TiCl2; 2 = (CumOS)2TiCl2; 3 = (t-BuOS)2Zr(CH2Ph)2; 4 = (CumOS)2Zr(CH2Ph)2); 5 = (t-BuOS)2Ti(OiPr)2; 6 = (t-BuOS)2Zr(OtBu)2; 7 = (t- ...
Synthesis of sustainable polyesters via ring opening polymerization promoted by phenoxy-imine aluminum complexes
(Universita degli studi di Salerno, 2019-02-04)
Aliphatic polyesters are emerging as an important class of materials alternatives to te petroleum-based polymers. They are often biodegradable and can be produced from renewable feedstocks. In this context, the developmentof ...
CO2 fixation in cyclic carbonates and polycarbonates by salen-like based metal complexes
(Universita degli studi di Salerno, 2019-02-06)
At the current rate of consumption of petroleum resources, they are predicted to be exhausted within the next century. For this reason, the development of new chemical processes using biorenewable resources is attracting ...