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dc.contributor.authorLuciano, Eramanno
dc.date.accessioned2016-08-08T08:37:02Z
dc.date.available2016-08-08T08:37:02Z
dc.date.issued2016-03-18
dc.identifier.urihttp://hdl.handle.net/10556/2176
dc.description2013 - 2014it_IT
dc.description.abstractIn this PhD work, a series of eight new group 4 metal complexes 1−8 (1 = (t- BuOS)2TiCl2; 2 = (CumOS)2TiCl2; 3 = (t-BuOS)2Zr(CH2Ph)2; 4 = (CumOS)2Zr(CH2Ph)2); 5 = (t-BuOS)2Ti(OiPr)2; 6 = (t-BuOS)2Zr(OtBu)2; 7 = (t- BuOS)2Hf(OtBu)2; 8 = (CumOS)2Zr(OtBu)2) supported by two phenolate bidentate ligands (t-BuOS−H = 4,6-di-tertbutyl- 2-phenylsulfanylphenol and CumOS−H = 4,6-dicumyl-2- phenylsulfanylphenol) were synthesized by the reaction of appropriate metal precursors with 2 equiv of the ligands. These complexes were characterized by means of 1H- and 13C-NMR spectroscopy and the complex 6 by X-ray diffraction... [edited by author]it_IT
dc.language.isoitit_IT
dc.publisherUniversita degli studi di Salernoit_IT
dc.subjectCatalisiit_IT
dc.subjectOlefineit_IT
dc.subjectEsteri cicliciit_IT
dc.titleSviluppo di nuovi sistemi catalitici dei metalli del gruppo 4 per la polimerizzazione di monomeri olefinici e polariit_IT
dc.typeDoctoral Thesisit_IT
dc.subject.miurCHIM/03 CHIMICA GENERALE E INORGANICAit_IT
dc.contributor.coordinatoreGuerra, Gaetanoit_IT
dc.description.cicloXIII n.s.it_IT
dc.contributor.tutorCapacchione, Carmineit_IT
dc.contributor.cotutorMilione, Stefanoit_IT
dc.identifier.DipartimentoChimica e Biologiait_IT
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