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Metathesis reactions catalyzed by ruthenium complexes for the self-healing of aeronautical materials
(Universita degli studi di Salerno, 2018-03-05)
In this PhD thesis work, Ruthenium catalysts were covalently and non-covalently linked to carbon-based nanomaterials, in order to give self-repairing ability to the aeronautical materials. These supported catalysts have ...
New metal catalysts for the synthesis of polyolefins and bioderived polymers
(Universita degli studi di Salerno, 2018-02-28)
The aim of PhD project is the synthesis of new metal catalysts active in the polymerization of polar
monomer and α-olefins. In the last decade, transition metal complexes bearing tetradentate bis(phenolato)
ligands are ...
Supramolecular Scaffolds for Biomimetic Catalysis
(Universita degli studi di Salerno, 2018-03-02)
This PhD thesis is concerned with the design, synthesis and the characterization of supramolecular scaffolds for biomimetic catalysis. Development of new organocatalytic systems based upon well-designed calix[4]arene ...
Thin coatings of biomaterials for hard tissue applications
(Universita degli studi di Salerno, 2018-03-05)
The goal of the present study is the production of new-generation coatings suitable for hard
tissue implants, intended to decrease the healing time, limit infections and rejections and
improve patients' life quality.
Materials ...
Development of new in vitro models based on the use of electrospun scaffolds and their imaging by multiphoton microscopy coupled with fluorescence lifetime imaging microscopy
(Universita degli studi di Salerno, 2018-02-22)
In this thesis, new possible applications of electrospun scaffolds are presented. Besides, the interaction of human dermal fibroblasts (HDFs) with the materials has been investigated using multiphoton microscopy (MPM) ...
Innovative applications of stable carbon isotope ratio in environmental and food chemistry
(Universita degli studi di Salerno, 2018-03-08)
In the last year, the stable isotope ratio analysis has become a useful tool with many applications in different scientific area. In particular the characteristic isotope signature of materials has permitted to identify ...
Calixarene based catalytic systems
(Universita degli studi di Salerno, 2018-02-22)
Catalysis is the essence of chemistry as it provides useful tools to make and brake chemical bonds. As nature has been a guide to many scientists, it’s no surprise that in the field of catalysis enzymes were a source of ...
Ruthenium metathesis precatalysts with unsymmetrical Nheterocyclic carbene (NHC) ligands
(Universita degli studi di Salerno, 2018-03-07)
Olefin metathesis is one of the most important chemical transformations for the formation
of carbon-carbon double bonds. The possibility to build up highly funtionalised alkenes
starting from simple olefins makes this ...
Phisical chemistry of plasmas and applications to cultural heritage and material science
(Universita degli studi di Salerno, 2018-03-04)
In this project, the attention has been focused on the laser ablation process and on laser induced plasmas spectroscopic study for two different technological applications. First of all, the analytical LIBS (Lase Induced ...
Development of iron-based catalysts for the coupling of carbon dioxide with epoxides
(Universita degli studi di Salerno, 2018-03-07)
Beside the environmental and energetic issues, carbon dioxide can
be considered as a resource. Many chemical transformations based
on CO2 as C-1 building block have been developed. The coupling
reaction of epoxides with ...