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Calixarene based catalytic systems
(Universita degli studi di Salerno, 2018-02-22)
Catalysis is the essence of chemistry as it provides useful tools to make and brake chemical bonds. As nature has been a guide to many scientists, it’s no surprise that in the field of catalysis enzymes were a source of ...
Small organic molecules for next generation electronics
(Universita degli studi di Salerno, 2016-03-16)
In this PhD thesis attention has been focused on the theoretical design of organic small
molecules for next generation electronics. The task of this thesis has concerned with the
theoretical analysis of the operational ...
Novel macrocyclic systems in asymmetric phase-transfer catalysis
(Universita degli studi di Salerno, 2017-02-27)
In the great realm of organic synthesis, phase-transfer catalysis (PTC) is a well recognized methodology which plays a key role both in industry and academia research. This process involves reactions that take place between ...
Ruthenium metathesis precatalysts with unsymmetrical Nheterocyclic carbene (NHC) ligands
(Universita degli studi di Salerno, 2018-03-07)
Olefin metathesis is one of the most important chemical transformations for the formation
of carbon-carbon double bonds. The possibility to build up highly funtionalised alkenes
starting from simple olefins makes this ...
Phisical chemistry of plasmas and applications to cultural heritage and material science
(Universita degli studi di Salerno, 2018-03-04)
In this project, the attention has been focused on the laser ablation process and on laser induced plasmas spectroscopic study for two different technological applications. First of all, the analytical LIBS (Lase Induced ...
Synthesis and properties of linear and cyclic peptoids
(Universita degli studi di Salerno, 2012-03-26)
Le strutture e le attività metaboliche di tutte le cellule si basano su una vasta gamma di molecole comprendenti: amminoacidi, carboidrati, lipidi e nucleotidi, insieme alle forme polimeriche di questi composti. Ognuna di ...
Redox proteins for the development of biosensors
(Universita degli studi di Salerno, 2011-02-21)
In recent years the field of chemical sensors and optical biosensors has been developed considereably. A biosensor is a device composed of a biological component (Borisov and Wolfbeis 2008) that interacts with a target ...
Enzymatic synthesis of macrolactones
(Universita degli studi di Salerno, 2011-02-24)
Macrolactones are a large and structurally diverse class of compounds. Natural products having a
macrolactone structure have been isolated from many natural sources such as plants, insects,
marine organism and bacteria. ...
New catalysts for ring-opening polymerization of cyclic esters
(Universita degli studi di Salerno, 2012-02-16)
The Ring-Opening Polymerization of cyclic esters by metal complexes via coordination-insertion mechanism represents the most effective and versatile method for preparing aliphatic polyesters with a good control in terms ...
Design e sintesi di analoghi delle azumammidi, potenti inibitori degli enzimi HDACs
(Universita degli studi di Salerno, 2011-03-07)
Le azumammidi sono cinque ciclopeptidi di origine marina, isolate nel 2003 da
Fusetani et al dalla spugna Mycale izuensis e brevettate dalla Yamanouchi Pharmaceutical.
L'interesse destato da questi metaboliti secondari ...