Please use this identifier to cite or link to this item: http://elea.unisa.it/xmlui/handle/10556/3087
Title: Development of iron-based catalysts for the coupling of carbon dioxide with epoxides
Authors: Della Monica, Francesco
Guerra, Gaetano
Capacchione, Carmine
Grassi, Alfonso
Keywords: Iron;Based;Catalysts
Issue Date: 7-Mar-2018
Publisher: Universita degli studi di Salerno
Abstract: Beside the environmental and energetic issues, carbon dioxide can be considered as a resource. Many chemical transformations based on CO2 as C-1 building block have been developed. The coupling reaction of epoxides with CO2 is one of the most attractive. An overview on the state of the art for metal-mediated process is provided. Particular enphasis is given to the iron-based systems, because it is an ideal candidate for the development of environmental and economic sustainable catalytic systems. It is the aim of this thesis to investigate the application of sulphur containing ligand based iron complexes, starting from the encouraging results reported by the research group of Capacchione in the case of the bis-thioether-tri-phenolate ligand based bimetallic Fe(III) complex.3 The synthesis and the complete characterization of five new thioether triphenolate ligands (L2-6), and of the corresponding bimetallic iron(III) complexes (2-6) is reported... [edited by author]
Description: 2016 - 2017
URI: http://hdl.handle.net/10556/3087
http://dx.doi.org/10.14273/unisa-1370
Appears in Collections:Chimica

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tesi F. Della Monica.pdftesi di dottorato8,65 MBAdobe PDFView/Open
abstract in inglese F. Della Monica.pdfabstract in inglese a cura dell’autore258,92 kBAdobe PDFView/Open
abstract in italiano F. Della Monica.pdfabstract in italiano a cura dell’autore258,84 kBAdobe PDFView/Open


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