Sfoglia Chimica per Titolo
Items 40-59 di 93
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Macrocycles: new properties and applications
(Universita degli studi di Salerno, 2023-06-02)Peptoids (polymers of N-substituted glycines) constitute a fascinating class of biomimetic oligoamides as peptides but exhibiting distinct structural and biological features. Cyclic peptoids, macrocycles derived from the ... -
Materiali ibridi e nanostrutturati derivati da copolimeri multiblocco polistirene-polibutadiene: sintesi e applicazioni
(Universita degli studi di Salerno, 2012-02-16)Scopo della presente tesi di Dottorato di Ricerca in Chimica, avente ampio carattere di esplorazione e innovazione, è stato quello di sviluppare materiali ibridi di natura organica ed inorganica con controllo della morfologia ... -
Mesoscale Modeling of Carbon Black/Polymer Interfaces: Linking Atomistic and Coarse-Grained Particle-Field Representations
(Universita degli studi di Salerno, 2020-02-11)The research activity, described in this Ph. D. thesis, was dedicated to the development of a novel carbon black (CB) primary particle model, with accurate morphology, to be used in coarse-grained (CG) molecular dynamics ... -
Metathesis reactions catalyzed by ruthenium complexes for the self-healing of aeronautical materials
(Universita degli studi di Salerno, 2018-03-05)In this PhD thesis work, Ruthenium catalysts were covalently and non-covalently linked to carbon-based nanomaterials, in order to give self-repairing ability to the aeronautical materials. These supported catalysts have ... -
Molecular bases of gluten toxicity and Relationship with the enzyme Transglutaminase in celiac disease
(Universita degli studi di Salerno, 2022-06-17)Celiac disease (CD) is a life-long gluten-sensitive immune-mediated disorder that primarily affects the small intestine of genetically susceptible individuals worldwide. Type 2 transglutaminase (TG2) has two crucial roles ... -
Molecular cartography of the metabolome of typical food products of the Basilicata region by using high resolution mass spectrometry
(Universita degli studi di Salerno, 2021-05-19)I marchi di Designazione di Origine Protetta (DOP) e di Indicazione Geografica Protetta (IGP), insieme a quello relative alle Specialità Tradizionali Garantite (STG), sono strumenti creati dall’Unione Europea (UE) che ... -
A molecular dymanics view of structure and reactivity
(Universita degli studi di Salerno, 2011-02-21)The eld of computer simulations has developed into a very important branch of science providing a guess at the interactions between molecules to obtain predictions of properties as accurate as required, subject to ... -
Molecular Properties Via Induced Current Densities
(Universita degli studi di Salerno, 2024-02-22)The PhD thesis written by Francesco F. Summa on Molecular Properties via Induced Current Densities is a careful report of a highly qualified and innovative research. Sixteen peer-reviewed publications on renowned journals ... -
Monitoraggio e conservazione dei beni culturali Lapidei:indagini diagnostiche mediante tecniche Di superficie e metodologie innovative per Interventi di manutenzione sostenibile
(Universita degli studi di Salerno, 2022-06-05)In recent decades, the historical and artistic heritage has undergone a greater degradation than in the past, in relation to the synergic action of atmospheric pollution, climate changes, and biological contamination. The ... -
New applications of Ester/Amide surrogates in organic synthesis
(Universita degli studi di Salerno, 2021-04-22)Masked esters/amides are scaffolds endowed with a great potential in the field of organic synthesis. This PhD project has been conceived, in the context of non-covalent organocatalysis, with the aim to exploit unsaturated ... -
New catalysts for ring-opening polymerization of cyclic esters
(Universita degli studi di Salerno, 2012-02-16)The Ring-Opening Polymerization of cyclic esters by metal complexes via coordination-insertion mechanism represents the most effective and versatile method for preparing aliphatic polyesters with a good control in terms ... -
New insights into peptoids' chemistry: synthesis, characterization and properties
(Universita degli studi di Salerno, 2016-05-11)My PhD research activity aimed to enrich the realm of peptoids1 with novel compounds and new insights into their behavior and properties, investigating their potential applications. A new class of cyclic “arylopeptoids” ... -
New insights on the ecology of underground ecosystems toward a sustainable management strategy
(Universita degli studi di Salerno, 2022-03-08)Underground cavities represent some of the less explored places on the planet (Lee et al., 2012). In fact, excluding the known carbonate dissolution/precipitation processes, leading to the formation of holes in the host ... -
New metal catalysts for Ring-Opening Polymerization of cyclic esters
(Universita degli studi di Salerno, 2022-05-28)I problemi ambientali ed economici legati ai polimeri derivanti da fonti petrolchimiche hanno spinto la ricerca accademica verso lo sviluppo di alternative green e degradabili rispetto alle plastiche convenzionali. I ... -
New metal catalysts for the synthesis of polyolefins and bioderived polymers
(Universita degli studi di Salerno, 2018-02-28)The aim of PhD project is the synthesis of new metal catalysts active in the polymerization of polar monomer and α-olefins. In the last decade, transition metal complexes bearing tetradentate bis(phenolato) ligands are ... -
New perspectives in phase transfer catalysis
(Universita degli studi di Salerno, 2020-02-11)The increasing demand for the stereoselective synthesis of bioactive compounds in both industrial and academic research has led to the rapid development of a variety of diastereo- and enantio-selective processes using phase ... -
New Technologies in Tires: From Layered Nanofillers to Metathesis Reactions
(Universita degli studi di Salerno, 2014-03-07)Tires are annually manufactured in more than one billion of artefacts and the ever increasing demand is on the basis of the efforts in finding new solutions for more performant, sustainable and durable products. This PhD ... -
Novel macrocyclic systems in asymmetric phase-transfer catalysis
(Universita degli studi di Salerno, 2017-02-27)In the great realm of organic synthesis, phase-transfer catalysis (PTC) is a well recognized methodology which plays a key role both in industry and academia research. This process involves reactions that take place between ... -
Olefin Metathesis Reactions Promoted by Ru-Catalysts with a Syn Substituted N-heterocyclic Carbene Backbone
(Universita degli studi di Salerno, 2014-03-06)The development of efficient catalytic systems dedicated to the formation of C−C double bonds from simple to highly functionalized alkenes represents a great challenge in modern organic synthesis. In addressing this ... -
Olive oil and oleate affect hepatic proteome and mitochondrial dynamics: in vivo and in vitro approaches
(Universita degli studi di Salerno, 2021-05-27)The Mediterranean diet (MD) has been pointed out as a nutritional approach to prevent metabolic disturbances leading to obesity, diabetes and liver steatosis. These properties have been largely attributed to oleic acid and ...
