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Synthesis of calixarene derivatives active towards proteic targets involved in tumor pathologies
(2016-03-15)
Over the last 30 years a growing interest has been direct toward the biomolecular recognition of calixarene derivatives and more in particular to the interaction with druggable target(s).1,2
The aim of this PhD thesis was ...
New insights into peptoids' chemistry: synthesis, characterization and properties
(2016-05-11)
My PhD research activity aimed to enrich the realm of peptoids1 with novel compounds and new insights into their behavior and properties, investigating their potential applications.
A new class of cyclic “arylopeptoids” ...
Small organic molecules for next generation electronics
(2016-03-16)
In this PhD thesis attention has been focused on the theoretical design of organic small
molecules for next generation electronics. The task of this thesis has concerned with the
theoretical analysis of the operational ...
Biodegradable and functional aliphatic co-polyesters
(2016-03-15)
Over the past decades, aliphatic polyesters have found rapidly increasing interest. Linear aliphatic polyesters, such as poly(glycolide) (PGA), poly(lactide) (PLA), poly(ε−caprolactone) (PCL) and their copolymers have found ...
Sustainable catalysis by polymer supported gold nanoparticles
(2016-03-16)
Gold Nanoparticles are nanomaterials whose properties are completely different from the ones of the bulk material. Nowadays many chemists have been using them as catalysts which work under mild conditions and respect the ...
Cavity Filling and Chirality Effects in Calixarene Threading
(2016-03-16)
In 2010, the Prof. Neri’s group showed that the calix[6]arene hosts were able to recognize dialkylammonium axles when they were coupled with the weakly coordinating Tetrakis[3,5 bis(triFluoromethyl)Phenyl]Borate (TFPB−) ...
Fluorescence-based sensors for the detection of biologically and environmentally relevant molecules
(2016-03-15)
Hydrogen sulfide (H2S) has been known for long time as a toxic molecule in biological systems. More recent studies have shown that mammals can produce H2S in a controlled fashion, suggesting that it’s important in maintaining ...
Sviluppo di nuovi sistemi catalitici dei metalli del gruppo 4 per la polimerizzazione di monomeri olefinici e polari
(2016-03-18)
In this PhD work, a series of eight new group 4 metal complexes 1−8 (1 = (t- BuOS)2TiCl2; 2 = (CumOS)2TiCl2; 3 = (t-BuOS)2Zr(CH2Ph)2; 4 = (CumOS)2Zr(CH2Ph)2); 5 = (t-BuOS)2Ti(OiPr)2; 6 = (t-BuOS)2Zr(OtBu)2; 7 = (t- ...